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71.
生物气CO_2还原途径中碳同位素分馏作用研究及应用 总被引:2,自引:0,他引:2
地质历史中,CO2/H2还原产甲烷作用对生物气的形成具有十分重要的意义。中国柴达木盆地第四系生物气主要为CO2/H2还原型生物气。笔者以CO2/H2还原生气理论为指导,进行不同初始碳同位素值和不同赋存状态碳源的生物模拟实验,研究CO2/H2还原产气过程中发生的碳同位素分馏作用。实验结果表明,产物中δ13CH4值与底物的δ13C值呈很好的正相关关系;在反应母质过量的情况下,碳源的赋存状态可以影响产物甲烷的碳同位素组成。以游离形式CO2还原产生的甲烷δ13C值,相对于以HCO3-、CO23-离子形式产生的甲烷δ13C值轻。通过柴达木盆地东部第四系生物气田实例分析,探讨了该区生物气的主要底物CO2的来源及赋存状态,对评价盆地生物气资源和有利勘探区预测有重要的参考价值。 相似文献
72.
成都经济区天降水与下渗水元素地球化学特征及土壤元素输入输出通量 总被引:2,自引:0,他引:2
论文研究了成都经济区天降水和下渗水中元素含量、在农田耕层中的输入输出通量及其影响因素.研究表明,研究区雨水中含有大量SO2-4、NO-3等酸性物质,雨水中SO2-4 >NO-3>Cl-.雨水中Ca2 和NH 4含量最高,且NH 4>Ca2 >K >Na >Mg2 .雨水的pH与阴、阳离子摩尔浓度差值具有显著相关性.下渗水中以Ca2 为主要阳离子,且Ca2 >Na >Mg2 >K >NH 4;HCO-3为主要阴离子,且HCO-3>NO-3>SO2-4>Cl->F-,下渗水pH与阳、阴离子摩尔浓度差值具有显著相关性.不同地区雨水中Pb>As>Cd>Se>Hg,下渗水中Pb>As>Se>Cd>Hg,因此,Cd、Pb、Se和Hg等元素累积在耕层中,而As则被下渗水携带迁移出耕层进入地下水.由降雨输入土壤中的Cd通量均大于下渗水输出Cd的通量,局部地区As下渗通量高于雨水输入通量的5.45~13.16倍.土壤中元素的下渗比与土壤质地、pH有关. 相似文献
73.
逯向阳 《沉积与特提斯地质》2008,28(4):14-17
烃源岩有机质丰度的恢复具有重要的现实和理论意义。笔者在对比多种方法的基础上,对大民屯凹陷的烃源岩的有机质丰度进行了恢复。 相似文献
74.
In this paper, the data on the paleoclimatic and paleoenvironmental changes during the Holocene are presented and a discussion
is made on a 225-cm-long sediment core from Ulungur Lake, located in Northwest China. The chronology is constructed from six
AMS radiocarbon dates on the bulk organic matter. On the basis of the analysis of ostracod assemblages and the shell stable
isotopes, the core is divided into three paleoclimatic and paleoenvironmental evolution stages: 9 985–5 250 cal.aB.P. stage
is the wettest phase of the core section. The climate changed from moderate-dry to cool-wet, and then to warm-wet in turn,
and the lake level rose accordingly, showing the characteristic of a high lake level. 5 250–1 255 cal.aB.P. stage was the
driest phase of the core sediment. The climate turned from the early warm-dry to the late warm-wet and the lake level fell
and rose again. Finally, the 1 255 cal.aB.P. stage was the medium stage of the section. The temperature was low and then increased
after the 1920s and the climate was dry. The whole climatic and environmental evolution records of Lake Ulungur were not only
in agreement with the sporopollen record of the same core but also in agreement with the record of environmental changes of
adjacent areas. It responded to regional environmental changes and global abrupt climate events, following the westerly climate
change mode on 100-year-scale, primarily with cold-wet and warmdry characteristics.
__________
Translated from Quaternary Sciences, 2007, 27(3):382–391 [译自:第四纪研究] 相似文献
75.
封闭体系有机质与有机碳氢氮恢复动力学研究 总被引:3,自引:0,他引:3
在封闭体系的条件下,对典型的Ⅰ、Ⅱ、Ⅲ型干酪根在热演化过程中的损失进行生烃动力学研究,获得了Ⅰ、Ⅱ、Ⅲ型干酪根的总量、有机碳、氢以及氮质量损失动力学参数。用Kinetics软件计算了封闭体系干酪根有机碳丰度、氢碳原子比和氮碳原子比的恢复系数。认为在对高成熟—过成熟干酪根进行生烃评价时,Ⅰ、Ⅲ型干酪根残余有机碳丰度需要进行恢复,而Ⅱ型干酪根残余有机碳丰度不需要恢复。三种类型干酪根的氢碳原子比均需要进行恢复。 相似文献
76.
Results from numerical investigations regarding the exchange of HNO3, NH3, and NH4NO3 between the atmosphere and the biosphere are presented. The investigations were performed with a modified inferential method which is based on the generally accepted micrometeorological ideas of the transfer of momentum, sensible heat and matter near the Earth's surface and the chemical reactions among these nitrogen compounds. This modified inferential method calculates the micrometeorological quantities (such as the friction velocity and the fluxes of sensible and latent heat), the height-invariant fluxes of the composed chemically conservative trace species with group concentrationsc
1=[HNO3]+[NH4NO3] (total nitrate),c
2=[NH3]+[NH4NO3] (total ammonia), andc
3=[HNO3]-[NH3] as well as the fluxes of the individual nitrogen compounds. The parameterization of the fluxes is based on the flux-gradient relationships in the turbulent region of the atmospheric surface layer. The modified inferential method requires only the data of wind velocity, temperature, humidity and concentrations (HNO3, NH3, and NH4NO3) measured at a reference height by stations of a monitoring network. 相似文献
77.
A dynamic box model was applied to study the characteristics of biogeochemical cycling of PO_4-P,NO_3-N,AOU,POC and PON in the southern Taiwan Strait region based on field data of the"Minnan Taiwan Bank Fishing Ground Upwelling Ecosystem Study" during the period of Dec.1987-Nov.1988.According to the unique hydrological and topographical features of the region,six boxesand three layers were considered in the model.The variation rates and fluxes of elements induced by hor-izontal current,upwelling,by diffusion,sinking of particles and biogeochemical processes were estimatedrespectively.Results further confirmed that upwellings had important effects in this region.Thenearshore upwelling areas had net input fluxes of nutrients brought by upwelling water,also had high de-pletion rates of nutrients and production rates of particulate organic matter and dissolved oxygen.Theabnormal net production of nutrients in the middle layer(10-30m) indicated the important role of bacte-ria in this high production region.Th 相似文献
78.
Santschi Peter H. Honeyman Bruce D. Quigley Matthew S. 《Aquatic Sciences - Research Across Boundaries》1993,55(4):230-239
In 1975 Paul Schindler produced the first oceanic trace metal scavenging model to explicitly include the role of surface chemistry as a control on trace metal water column residence times. The eighteen years that have elapsed since the publication of Schindler's seminal paper have seen the development of a variety of oceanic scavenging models; yet, the fundamental insight of his Zero-order Model remains the benchmark. This paper describes the role of Paul Schindler's work on surface chemistry in providing a framework for the current generation of trace element scavenging models. 相似文献
79.
在"碳中和"目标的驱动下,全球能源系统向清洁化、低碳化甚至无碳化发展已是大势所趋。针对向清洁能源转型的需求,采用了统计对比、分类汇总、综合分析等方法,分析研究了关键矿产在电池、电网、低碳发电和氢能等行业中的作用和需求。结合当前关键矿产产量的地理集中度高、项目开发周期长、资源质量下降等矿产供应和投资计划不能满足清洁能源转型的需求等问题,提出确保关键矿产多样性供应,推动价值链各环节的技术创新,扩大回收利用,增强供应链弹性和市场透明度,将更高的环境、社会和治理标准纳入主流程及加强生产者和消费者之间的国际合作等建议。 相似文献
80.
Particulate content of savanna fire emissions 总被引:9,自引:0,他引:9
Hélène Cachier Catherine Liousse Patrick Buat-Menard Annie Gaudichet 《Journal of Atmospheric Chemistry》1995,22(1-2):123-148
As part of the FOS-DECAFE experiment at Lamto (Ivory Coast) in January 1991, various aerosol samples were collected at ground level near prescribed fires or under local background conditions, to characterize the emissions of particulate matter from the burning of savanna vegetation. This paper deals with total aerosol (TPM) and carbon measurements. Detailed trace element and polycyclic hydrocarbon data are discussed in other papers presented in this issue.Near the fire plumes, the aerosols from biomass burning are primarily of a carbonaceous nature (C%70% of the aerosol mass) and consist predominantly of submicron particles (more than 90% in mass.) They are characterized by their organic nature (black to total carbon ratio Cb/Ct in the range 3–20%) and their high potassium content (K/Cb0.6). These aerosols undergo aging during their first minutes in the atmosphere causing slight alterations in their size distribution and chemical composition. However, they remain enriched in potassium (K/Cb=0.21) and pyrene, a polycyclic aromatic hydrocarbon, such that both of these species may be used as tracers of savanna burning aerosols. We show that during this period of the year, the background atmosphere experiences severe pollution from both terrigenous sources and regional biomass burning (44% of the aerosol). Daynight variations of the background carbon concentrations suggest that fire ignition and spreading occur primarily during the day. Simultaneous TPM and CO2 real-time measurements point to a temporal and spatial heterogeneity of the burning so that the ratio of the above background concentrations (TPM/CO2) varies from 2 to 400 g/kg C. Smoldering processes are intense sources of particles but particulate emissions may also be important during the rapidly spreading heading fires in connection with the generation of heavy brown smoke. We propose emission factor values (EF) for aerosols from the savanna biomass burning aerosols: EF (TPM)=11.4±4.6 and 69±25 g/kg Cdry plant and EF(Ct)=7.4±3.4 and 56±16 g C/kg Cdry plant for flaming and smoldering processes respectively. In these estimates, the range of uncertainty is mostly due to the intra-fire variability. These values are significantly lower than those reported in the literature for the combustion of other types of vegetation. But due to the large amounts of vegetation biomass being burnt in African savannas, the annual flux of particulate carbon into the atmosphere is estimated to be of the order of 8 Tg C, which rivals particulate carbon emissions from anthropogenic activities in temperate regions. 相似文献